I don't think you can directly. If I understand your question, you want the SQL style permission of (deny_datawriter and deny_datareader etc. per user).
You can possibly achieve the same via permissions (although it does depend on your situation).
Right click the access file, and under the security tab set the permissions (read/write/full control etc). Or, you could even set this up as groups if it's for many people/user types. Then you just set the appropriate groups permission.
It may require you moving this file to a shared location for this to work though (which may not be an option for you).