You can use xpdf to extract the scan images from inside your PDF files
Then use imagemagick to convert each image into pbm format:
convert page-000.png page-000.pbm
Then convert your pbm images into djvu pages with djvulibre.
cjb2 -clean page-000.pbm page-000.djvu
Finally adding your new page to the final document
djvm -i page.djvu page-000.djvu
The process is partially explained here: Creating a DjVu file