Contact your ISP and tell them you would like to add an SPF record to your DNS records. SPF or Sender Framework Policy in short sets an IP, or list of IPsas authorized email distributors for your domain. Sender Policy Framework (SPF) is an email validation system designed to prevent email spam by detecting email spoofing, a common vulnerability, by verifying sender IP addresses. SPF allows administrators to specify which hosts are allowed to send mail from a given domain by creating a specific SPF record (or TXT record) in the Domain Name System (DNS). Mail exchangers use the DNS to check that mail from a given domain is being sent by a host sanctioned by that domain's administrators.
Sender Policy Framework is defined in IETF publication RFC 4408 Wikipedia Full Article